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The Scorpion

Real Name: Mac Gargan
Voice: Martin Landau/Richard Moll
First Appearance: The Sting Of The Scorpion

The Scorpion started out as private investigator working for J. Jonah Jameson to try and discover if there was any connection between Peter Parker and Spider-Man. Jameson later offered Gargan the opportunity to publicly defeat Spider-Man by undergoing an operation to splice his genetic codes with those of a Scorpion.

After he defeated Spider-Man, he discovered the operation has turned him into a freak. Desperate to find a cure for his condition, Scorpion went on a rampage in New York, until Spider-Man stopped him, with the help of Jameson.

After joining the Insidious Six and failing to kill Spider-Man yet again, Scorpion focused his efforts on finding a cure, so he could marry Sarah, his girlfriend