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Madame Web

Real Name: Jim Rhodes
Voice: James Avery
First Appearance: Venom Returns
Jim Rhodes is the head of security for Stark Industries. Rhodes was supervising the inter-dimensional travel experiment before he and his men where attacked by Venom, and later Carnage. Spider-Man and War Machine fought the symbiotes before they escaped. Injured, War Machine had no choice but to contact Iron Man to help get the transporter back.

For more on War Machine, check out his Iron Man Bio